Thanks for the responses. I got a small sample of .75 nylon and 1.0 UHMW today and it machines amazingly well, I would say better than hardwood. It's a little bit dangerous in smaller holes/cutouts as the router bit sometimes nearly grabbed into the plastic. Maybe the router bit is getting dull.
Probably not that bad - UHMW and PU (polyurethanes) in particular are very "grabby" so try to reduce the cut to the bare minimum (i.e. less than 1/2 the diameter of the cutter you are using) and avoid climb milling with a hand router at all costs
They told me that CNC machining of these plastics is done at very high speeds to avoid local melting, at much higher speeds than woodworking tools. I did not know if that was true but I took it very easy anyway just to be sure and had the router bit remove only a little layer at each pass and never stayed at one spot or redid the same area within seconds. The sides and edges all came out fine.
On CNC routers you aim the do the first (roughing) pass to within something like 0.1 to 0.5mm of the finish size and this pass is done at high feed speed, but relatively low spindle speed, e.g. for UHMW-PE 1000 grade something like 6 to 12 metres feed rate, 12,000 rpm feed rate on a 20mm diameter tool. This will generate a stream of tight curl chips rather than dust and therefore you don't get churning of waste in the cut which overheats and dulls bits. A second, finishing cut is then required because all plastics compress and spring back when cut and in addition the surface formed by the roughing cut isn't the best. Clearing swarf on the second pass can cause problems so vacuum extraction is recommended. Weld back is a phenomenon associated with nylons, acrylics and polycarbonates - it doesn't really occur with UHMW-PE.
However there is a problem: the roundover edge to flat transition is never smooth. The lines are all noticeable and can be easily felt and there is no way to sand them smooth I think. I hope I don't need a chemical to polish these transition lines smooth (or other areas of the part when needed). Any solution or recommendation?
You could try to find a cutter manufacturer who sells a roundover bit with a transitioning edge to the cutter, i.e. one which tapers out of the radius. We have one manufacturer here in the UK who does these, Titman, but they aren't cheap because they are industrial tools. As Patrick says bearing cutters always vibrate a little which isn't a problem on wood where you can sand afterwards, so guide bush and plain cutter is a good approach.
IHMO few plastics take to being sanded, although Corian and other solid surface materials are very good (as are acrylics). The problem is that most plastics tend to compress then spring back too easily under cutting/sanding (it's called polymer memory) - but you can often scrape plastics (card scraper) and
some respond to a heat gun, e.g. acrylic and polycarbonate, but I've had variable/limited success with UHMW-PE and nylon/Delrin. One thing you mention is that Corian is brittle - it will chip if droppen on edge onto a concrete floor. I think pretty much all the countertop materials like Corian will be the same (and I've used several, e.g. Formica, Wilsonart, LG, Staron, Iro, Schock, etc) because they are acrylic polymers or co-polymers and acrylics are hard but brittle. As to its' strength, though, it is not the norm to back countertops over their entire width/length with sheet materail unless you are surfacing with 3mm (1/8in) or 6mm (1/4in) solid surface stock because such a backer will tend to bow very very quickly if not fixed down straight away. What we tend to do is to make up countertops from 12mm (1/2in) solid surface material with a 20mm (2in) wide strip of MR-MDF glued along both edges and the ends (silicone sealant) and then build the drop edges by adding another strip of 12mm stock. That makes for a strong and durable countertop which won't move so much
Regards
Phil