It's certainly possible he was using that much DC to pyro-craft. If the 'equipment' was 'home crafted', it is far more likely he was using AC. Neon sign transformers were fun to play with in school to make 'Tesla Toys'....
The fundamental distinction between AC and DC is whether the voltage measured across the same two points fluctuates (Alternates) or remains constant (direct). Voltage coming 'directly' out of a transformer is AC by it's very nature. The induction process relies on the fluctuation of pulses flowing through the input winding (usually called a primary) in order to transfer them to the output winding (usually called a secondary). The frequency or pulses per second is transparently transferred across.
That being said, in a purest sense, DC isn't really 'pure' DC unless it comes out of a battery.
The DC in your car battery is really DC. The DC coming out of the alternator that keeps it charged and powers the vehicle when it is running is more along the lines of 'close enough to true DC', or what is often called 'ripple DC'.
I was taught that anything with a measured frequency greater than 2800 cps can be regarded as DC, especially for power purposes.
When there is a need to convert it to DC, devices classified as 'rectifiers' are used to accomplish the conversion. A basic rectifier is called a diode, and only allows current to flow in one direction. 4 diodes, connected to form a circle create what is called a 'full wave bridge rectifer' and is a very common way to convert AC to DC. The modern semiconductor of choice in power conversion is what they call an SCR, or silicon control rectifier.